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3-CARENE

CAS No.
13466-78-9
Chemical Name:
3-CARENE
Synonyms
carene;DELTA-3-CARENE;Car-3-ene;3,7,7-TRIMETHYLBICYCLO[4.1.0]HEPT-3-ENE;D-CARENE;delta-3-CARENE, NATURAL;3-Karen;3-CARENE;3-CARVENE;FEMA 3821
CBNumber:
CB7349182
Molecular Formula:
C10H16
Molecular Weight:
136.23
MDL Number:
MFCD00001315
MOL File:
13466-78-9.mol
MSDS File:
SDS
Last updated:2023-06-08 09:02:56

3-CARENE Properties

Melting point 25°C
Boiling point 168-169 °C/705 mmHg (lit.)
Density 0.857 g/mL at 25 °C (lit.)
FEMA 3821 | DELTA-3-CARENE
refractive index n20/D 1.474(lit.)
Flash point 115 °F
storage temp. 2-8°C
solubility Chloroform: Soluble; Methanol: Soluble
form Liquid
color Clear colorless to slightly yellow
Odor at 100.00 %. citrus terpenic herbal pine solvent resinous phenolic cypress medicinal woody
Odor Type citrus
optical activity [α]20/D +15°, neat
JECFA Number 1342
Merck 1836
Stability Stable. Flammable. Incompatible with strong oxidizing agents.
LogP 4.38
Substances Added to Food (formerly EAFUS) 3-CARENE
EWG's Food Scores 2-5
FDA UNII H2M15SNR6N
EPA Substance Registry System 3-Carene (13466-78-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H226-H304-H315-H317-H412
Precautionary statements  P210-P273-P280-P301+P310-P303+P361+P353-P331
Hazard Codes  Xi,N,Xn
Risk Statements  10-43-50/53-65-38-52/53
Safety Statements  16-26-36/37-60-61-62-37-24
RIDADR  UN 2319 3/PG 3
WGK Germany  2
RTECS  FH8400000
HazardClass  3.2
PackingGroup  III
HS Code  29021990
NFPA 704
2
1 0

3-CARENE price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 115576 3-Carene 90% 13466-78-9 25ml $50.2 2024-03-01 Buy
Sigma-Aldrich 115576 3-Carene 90% 13466-78-9 1l $149 2024-03-01 Buy
Sigma-Aldrich CRM40752 3-Carene solution certifiedreferencematerial,2000?μg/mLinmethanol,ampuleof1?mL 13466-78-9 1mL $127 2022-05-15 Buy
TCI Chemical C0047 (+)-3-Carene >90.0%(GC) 13466-78-9 25mL $16 2021-12-16 Buy
TCI Chemical C0047 (+)-3-Carene >90.0%(GC) 13466-78-9 500mL $37 2021-12-16 Buy
Product number Packaging Price Buy
115576 25ml $50.2 Buy
115576 1l $149 Buy
CRM40752 1mL $127 Buy
C0047 25mL $16 Buy
C0047 500mL $37 Buy

3-CARENE Chemical Properties,Uses,Production

Description

Hydroperoxides of Δ-3-carene are allergens contained in turpentine. Occupational exposure occurs in painters, varnishers, or in ceramic decoration. The percentage of Δ-3-Carene is higher in Indonesian turpentine than in Portugese.

Description

(±)-3-Carene is a bicyclic monoterpene found in a variety of plants, including Cannabis. It decreases phagocytosis by rat alveolar macrophages when used at a concentration of 0.5 μM and decreases their viability at a concentration of 5 μM. (±)-3-Carene increases the expression and activity of alkaline phosphatase in mouse osteoblastic MC3T3-E1 subclone 4 cells, indicating induction of osteoblastic differentiation. It also induces calcium formation and increases the expression of osteopontin and type I collagen, which are related to osteoblast mineralization. (±)-3-Carene induces bronchoconstriction in isolated guinea pig lungs when exposed at an air concentration of 3,000 mg/m3.

Chemical Properties

3-Carene has a sweet, pungent turpentine-like taste.

Chemical Properties

Clear, colorless liquid. Stable to approx- imately 250C, resinifies with oxygen. Insoluble in water; miscible with organic solutions. Com- bustible.

Occurrence

Reported present in basil oil, bell pepper, bilberry, black currant berry juice and buds, fennel oil, grapefruit juice, kumquat peel oil, lemon peel oil, lime peel oil (cold pressed and distilled), lovage seed, mandarin peel oil, orange juice, orange peel oil, orange (bitter) peel oil, tangerine peel oil and other natural products.

Uses

Solvent, intermediate. 3-Carene is a mutagenic compound that may be found in the fumes of heating freshly cut spruce and birch chips. 3-Carene is also found i many esential oils and it inhibits acetylcholinesterase activity.

Preparation

Extracted from the pine tree oil.

Definition

A terpene hydrocarbon with both a 6-member and 3-member ring.

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 5255, 1984 DOI: 10.1016/S0040-4039(01)81577-X

General Description

Colorless liquid with a sweet, turpentine-like odor. Floats on water.

Reactivity Profile

3-CARENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. Will attack some forms of plastics [USCG, 1999].

Health Hazard

Inhalation causes headache, confusion, respiratory distress. Ingestion irritates entire digestive system and may injure kidneys; if liquid enters lungs, it causes severe pneumonitis. Contact with eyes or skin causes irritation.

Contact allergens

Hydroperoxides of D-3-carene are allergens contained in turpentine. Occupational exposure occurs in painters, varnishers, or ceramic decoration. The percentage of D-3-carene is higher in Indonesian than in Portuguese turpentine.

3-CARENE Preparation Products And Raw materials

Global( 203)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15956 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21688 55
Shanghai Zheyan Biotech Co., Ltd.
18017610038 zheyansh@163.com CHINA 3620 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 10247 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5909 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58
TargetMol Chemicals Inc.
+1-781-999-5354 +1-00000000000 marketing@targetmol.com United States 19892 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 9126 58

View Lastest Price from 3-CARENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-Carene  pictures 2020-02-26 3-Carene
13466-78-9
US $0.00-0.00 / Kg 100G 99.0%+ 100 tons Shaanxi Dideu Medichem Co. Ltd
	3-CARENE pictures 2020-01-08 3-CARENE
13466-78-9
US $2.00 / KG 1KG 98% 100g , 1kg, 5kg , 50kg Career Henan Chemical Co
  • 3-Carene  pictures
  • 3-Carene
    13466-78-9
  • US $0.00-0.00 / Kg
  • 99.0%+
  • Shaanxi Dideu Medichem Co. Ltd
  • 	3-CARENE pictures
  • 3-CARENE
    13466-78-9
  • US $2.00 / KG
  • 98%
  • Career Henan Chemical Co
3-Carene, stabilized, 90% δ-3-carene,3,7,7-trimethylbicyclohept-3-ene CARENE, Delta-3-(SG) DELTA-CARENE CAREN-(3), ROH 3-CARVENE 3-CARENE WITH GC 3-Karen (jfr terpener) δ3-Carene, 3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene 3,7,7-Trimethyl-3-norcarene 3-Carene 90% 3,7,7-trimethyl-3-norcaren 3,7,7-trimethyl-bicyclo(4.1.0)hept-3-en 3,7,7-trimethyl-bicyclo[4.1.0]hept-3-en 3-Carene,90%,stabilized 3-Carene,δ3-Carene, 3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene 3-Carene, stabilized, 90% 1LT 3-Carene, stabilized, 90% 25ML 3,7,7-Trimethylbicyclo(4.1.0)hept-3-ene for synthesis 3-delta-carene 3-Karen 3-Norcarene, 3,7,7-trimethyl- 4,7,7-Trimethyl-3-norcarene Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl- FEMA 3821 CARENE, DELTA-3 3,7,7-TRIMETHYLBICYCLO[4.1.0]-3-HEPTENE 3-CARENE 3-CARENE (DELTA) bicyclo[4.1.0]hept-3-ene,3,7,7-trimethyl- delta(Sup3)-Carene DELTA-car-3-ene Isodiprene S-3-Carene 4,7,7-trimethylbicyclo[4.1.0]hept-3-ene (+)-3-Carene> DodecaethyleneGlycolMonomethylEther> 1,6-Bis(acryloyloxy)-2,2,3,3,4,4,5,5-octafluorohexane > N-Butyl-N-(4-hydroxybutyl)nitrosamine > 90.0%(GC) 3-CARENE USP/EP/BP Natural Terpene Delta-Carene CAS 13466-78-9 94% in Flavor 7-DIMETHOXY-5-HYDROXYFLAVONE D-CARENE delta-3-CARENE, NATURAL DELTA-3-CARENE 3,7,7-TRIMETHYLBICYCLO[4.1.0]HEPT-3-ENE Car-3-ene carene 13466-78-9 Chiral Building Blocks Asymmetric Synthesis Organic Building Blocks Alkenes Bicyclic Monoterpenes Biochemistry Terpenes Miscellaneous