ChemicalBook >> CAS DataBase List >>(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE structure

CAS No.: 494227-36-0

Chemical Name:: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

Synonyms: MANDYPHOS SL-M003-1;]-1,1'-bis[di(3,5-trifL;(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phos;(SP,SμP)-1,1μ-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-,2'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene;(SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoroMethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(diMethylaMino)benzyl]ferrocene;(R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE;(1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene;(1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene

CBNumber:: CB9671090

Molecular Formula:: C60H42F24FeN2P210*

Molecular Weight:: 1364.74

MDL Number:: MFCD04117703

MOL File:: 494227-36-0.mol

Last updated:2023-04-23 13:52:06

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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Properties

alpha	-250.2° (c 1.0, CHCl3)
form	solid
color	orange-red
Stability	store cold

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P280-P301+P312-P302+P352-P305+P351+P338
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
HS Code	29319090

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE price More Price(10)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	73467	(SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%	494227-36-0	100mg	$94	2021-12-16	Buy
Sigma-Aldrich	73467	(SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%	494227-36-0	500mg	$378	2021-12-16	Buy
Strem Chemicals	26-0244	(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%	494227-36-0	100mg	$96	2024-03-01	Buy
Strem Chemicals	26-0244	(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%	494227-36-0	500mg	$355	2024-03-01	Buy
Strem Chemicals	26-0244	(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%	494227-36-0	2g	$1207	2024-03-01	Buy

Product number	Packaging	Price	Buy
73467	100mg	$94	Buy
73467	500mg	$378	Buy
26-0244	100mg	$96	Buy
26-0244	500mg	$355	Buy
26-0244	2g	$1207	Buy

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Chemical Properties,Uses,Production

Reaction

Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
Ligand for Rh-catalyzed hydrogenation of αand β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3diketones.
Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
Ligand for Cu-catalyzed enantioselective hydroboration of αand β-unsaturated esters and nitriles.

Chemical Properties

Orange powder

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Preparation Products And Raw materials

Raw materials

Preparation Products

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Suppliers

Global( 35)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15954	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32715	60
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58
Henan Allgreen Chemical Co.,LTD	+86-37155567971 +86-13633837469	info@allgreenchem.com	China	5986	58
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6116	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	52927	58
Mainchem Co., Ltd.	+86-0592-6210733	sale@mainchem.com	China	32360	55
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	021-61259108 18621169109	market03@meryer.com	China	40240	62

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Henan Allgreen Chemical Co.,LTD	58
Shaoxin Catsyn Co., Ltd.	58
Aladdin Scientific	58
Mainchem Co., Ltd.	55
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62

View Lastest Price from (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-01-13	(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE 494227-36-0	US $1.00 / KG	1KG	98%	200kgs	Career Henan Chemical Co

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
494227-36-0
US $1.00 / KG
98%
Career Henan Chemical Co

494227-36-0((ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE)Related Search:

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (S)-1-{(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}ETHYLDICYCLO (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

1,1'-DIETHYLFERROCENE Ferrocene (R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

1,1'-DIMETHYLFERROCENE 1,1'-Bis(diphenylphosphino)ferrocene (3-AMINOPROPYL)DIPHENYLPHOSPHINE N,N-Dimethylaminomethylferrocene (R)-(-)-ALPHA-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]BENZYLAMINE

(R)-(S)-BPPFA BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)PHOSPHINE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

1of4

MANDYPHOS SL-M003-1 (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl (S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-trifluoromethylphenyl)phosphino)ferrocene (R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE (S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-DI[BIS(3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINO]FERROCENE (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene,min.97% (r,r)-1,1'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2'-bis[(r)-α-(dimethylamino)benzyl]ferrocene (acc to cas) (αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-,2'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene (SP,SμP)-1,1μ-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene Mandyphos SL-M003-1, (1R,1μR)-1,1μ-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS) (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene, min. 97% (S,S)-(-)-2,2'-Bis[(R)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-bis[di(3,5-trifluoroMethylphenyl)phosphino]ferrocene (aR,aR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di(bis-(3,5-trifluoromethyl)phenyl)-phosphino]ferrocene (aR,aR)-2,2'-Bis(a-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di-(bis(3,5-trifluoromethyl)-phenyl)phosphino]-ferrocene (1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phos ]-1,1'-bis[di(3,5-trifL (S,S)Fc-1,1’-Bis[bis[3,5-bis(trifluoromethyl)phenyl] phosphino]-2,2’-bis[(R,R)C-(N,N-dimethylamino) phenylmethyl]ferrocene (SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoroMethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(diMethylaMino)benzyl]ferrocene (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene (1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene 494227-36-0 C60H42F24FeN2P2 Solvias Ligands Privileged Ligands Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Phosphine Ferrocene Series Mandyphos Series