페닐하이드라진 수화염화물
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페닐하이드라진 수화염화물 속성
- 녹는점
- 250-254 °C (dec.)(lit.)
- 끓는 점
- 236.22°C (rough estimate)
- 밀도
- 1.1672 (rough estimate)
- 굴절률
- 1.5210 (estimate)
- 저장 조건
- Store below +30°C.
- 용해도
- H2O: 용해성50mg/mL
- 물리적 상태
- 미세 결정성 분말
- 색상
- 흰색에서 밝은 노란색 또는 분홍빛이 도는 베이지색
- 수소이온지수(pH)
- 2.6-2.9 (50g/l, H2O)
- 수용성
- 50g/L(20℃)
- Merck
- 14,7293
- BRN
- 3594958
- 안정성
- 안정적인. 대부분의 일반적인 금속과 호환되지 않습니다.
- InChIKey
- JOVOSQBPPZZESK-UHFFFAOYSA-N
- CAS 데이터베이스
- 59-88-1(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | T,N | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 45-23/24/25-36/38-43-48/23/24/25-50-68 | ||
| 안전지침서 | 53-45-61 | ||
| 유엔번호(UN No.) | UN 2811 6.1/PG 3 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | MV9000000 | ||
| F 고인화성물질 | 3-8-10-23 | ||
| TSCA | Yes | ||
| 위험 등급 | 6.1 | ||
| 포장분류 | III | ||
| HS 번호 | 29280090 | ||
| 기존화학 물질 | KE-28380 |
페닐하이드라진 수화염화물 C화학적 특성, 용도, 생산
용도
Phenylhydrazine hydrochloride is used as a selective mannosidase inhibitor. It is used in the study of tyrosine phosphorylation of janus protein tyrosine kinase in the EPO-responsive normal erythroblastoid cells of anemic mice. It is used in steroid assays and as an N-protecting reagent. Its free base, phenylhydrazine is used to prepare indoles, which find application as intermediates in the synthesis of various dyes and pharmaceuticals.일반 설명
White to tan solid with a weak aromatic odor.공기와 물의 반응
Forms corrosive acidic solutions.반응 프로필
Phenylhydrazine hydrochloride may be corrosive to metals [USCG, 1999].건강위험
Phenylhydrazine hydrochloride is poisonous if swallowed or if fumes are inhaled. Dust is irritating to eyes, nose, and throat. Phenylhydrazine is a chronic poison. Phenylhydrazine is an industrial substance suspect of carcinogenic potential for humans.화재위험
Toxic and irritating hydrogen chloride and oxides of nitrogen may be produced in fire. May be corrosive to metals. Hazardous polymerization may not occur.Safety Profile
Poison by ingestion, intraperitoneal, and subcutaneous routes. Experimental reproductive effects. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and HCl.잠재적 노출
Phenylhydrazine is a widely used reagent in conjunction with sugars, aldehydes, and ketones. In addition, to its use in the synthesis of dyes; pharmaceuticals, such as antipyrin; cryogenin, and pyramidone; and other organic chemicals. The hydrochloride salt is used in the treatment of polycythemia vera.운송 방법
UN2572 Phenylhydrazine, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.Purification Methods
Dissolve 100g of phenylhydrazine hydrochloride in 200mL of warm H2O (60-70o) during 1-3hours, then add 1L of boiling EtOH. The solution is filtered, while still hot, through Whatman No 2 filter paper and cooled in a refrigerator. The precipitate is collected on a medium sintered-glass filter and recrystallised twice this way, then washed with cold EtOH, dried thoroughly and stored in a stoppered brown bottle. [Peterson et al. Anal Chem 29 144 1957.] Hough, Powell and Woods [J Chem Soc 4799 1956] boiled the hydrochloride with three times its weight of water, filtered hot (charcoal), added one-third volume of concentrated HCl and cooled to 0o. The crystals were washed with acetone, and dried over P2O5 under vacuum. The salt has also been crystallised from 95% EtOH, and it can be sublimed. [Coleman Org Synth Coll Vol I 442 1941, Beilstein 15 III 71.]비 호환성
Phenylhydrazine is very reactive with carbonyl compounds, strong oxidizers; strong bases; alkali metals; ammonia, lead dioxide (violent). Attacks copper salts, nickel, and chromates.폐기물 처리
Controlled incineration whereby oxides of nitrogen are removed from the effluent gas by scrubber, catalytic or thermal device.페닐하이드라진 수화염화물 준비 용품 및 원자재
원자재
준비 용품
3-HYDROXY-1-PHENYL-6-PYRIDAZONE
5-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-AMINE
(5-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-YL)METHANOL
1-페닐-5-(트리플루오로메틸)-1H-피라졸-4-카르복시산
1-PHENYL-3-THIOSEMICARBAZIDE
5-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBONITRILE
1-PHENYL-5-(TRIFLUOROMETHYL)PYRAZOLE-4-CARBONYL CHLORIDE
ETHYL 2-PHENYL-3-(TRIFLUOROMETHYL)PYRAZOLE-4-CARBOXYLATE
(5-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-YL)METHANAMINE
1,3,3-TRIMETHYLINDOLINOBENZOPYRYLOSPIRAN
Triazophos E.C.
4-Nitrophenylhydrazine
SULFENTRAZONE
트리아조포스
5-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBOXAMIDE
Tryptophol
페닐하이드라진 수화염화물 공급 업체
글로벌( 411)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| TCI AMERICA | 800-4238616 |
sales@tciamerica.com | Americas | 23662 | 75 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 |
peter@yan-xi.com | China | 6000 | 58 |
| Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 |
daisy@crovellbio.com | China | 5963 | 58 |
| Hebei Duling International Trade Co. LTD | +8618712993135 |
sales01@hbduling.cn | China | 15743 | 58 |
| Wuhan Quanjinci New Material Co.,Ltd. | +8615271838296 |
kyra@quanjinci.com | China | 1534 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21689 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 |
jack.li@time-chemicals.com | China | 1807 | 55 |
| Hubei XinRunde Chemical Co., Ltd. | +8615102730682 |
bruce@xrdchem.cn | CHINA | 566 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 |
info@tnjchem.com | China | 2989 | 55 |