프탈산디알릴모노머

프탈산디알릴모노머
프탈산디알릴모노머 구조식 이미지
카스 번호:
131-17-9
한글명:
프탈산디알릴모노머
동의어(한글):
다이알릴프탈산;디알릴프탈산;프탈산디알릴모노머;다이알릴프탈산;디알릴프탈산;다이알릴 프탈산;1,2-벤젠다이카르복실 산, 다이-2-프로페닐 에스터;1,2-벤젠다이카복실산, 1,2-다이-2-프로펜-1-일 에스터;1,2-벤젠다이카복실산, 다이-2-프로펜일 에스터;DAP;Dapon 35;Dapon R;NCI-C50657;o-프탈 산 다이알릴 에스터;o-프탈산, 다이알릴 에스터;다이알릴 프탈레이트;다이알릴에스터 프탈 산;다이프로프-2-엔일 벤젠-1,2-다이카복실레이트;알릴 프탈레이트;알릴 프탈산
상품명:
Diallyl phthalate
동의어(영문):
DAP;Dially Phthalate;DAP(Diallyl Phthalate);Dappu;daponr;Dapon R;dapon35;Dapon 35;RX 1-501N;NCI-C50657
CBNumber:
CB0246486
분자식:
C14H14O4
포뮬러 무게:
246.26
MOL 파일:
131-17-9.mol
MSDS 파일:
SDS

프탈산디알릴모노머 속성

녹는점
-70 °C
끓는 점
165-167 °C/5 mmHg (lit.)
밀도
1.121 g/mL at 25 °C (lit.)
증기 밀도
8.3 (vs air)
증기압
2.3 mm Hg ( 150 °C)
굴절률
n20/D 1.519(lit.)
인화점
>230 °F
저장 조건
Inert atmosphere,2-8°C
용해도
0.18g/L
물리적 상태
액체
색상
무색투명~연황색
냄새
가벼운 냄새
수용성
6g/L(20℃)
BRN
1880877
InChIKey
QUDWYFHPNIMBFC-UHFFFAOYSA-N
LogP
3.23 at 20℃
CAS 데이터베이스
131-17-9(CAS DataBase Reference)
NIST
1,2-Benzenedicarboxylic acid, di-2-propenyl ester(131-17-9)
EPA
Diallyl phthalate (131-17-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,N
위험 카페고리 넘버 22-50/53
안전지침서 24/25-60-61
유엔번호(UN No.) UN 3082 9/PG 3
WGK 독일 2
RTECS 번호 CZ4200000
F 고인화성물질 19
자연 발화 온도 725 °F
TSCA Yes
위험 등급 9
포장분류 III
HS 번호 29173400
유해 물질 데이터 131-17-9(Hazardous Substances Data)
기존화학 물질 KE-02288
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
NFPA 704
1
1 1

프탈산디알릴모노머 MSDS


1,2-Benzenedicarboxylic acid di-2-propenyl ester

프탈산디알릴모노머 C화학적 특성, 용도, 생산

화학적 성질

clear colourless to light yellow liquid

용도

Diallyl Phthalate is used as a reagent in ring-closing ruthenium based reactions.

제조 방법

Diallyl phthalate (DAP) is prepared by reaction of phthalic anhydride and allyl alcohol:

131-17-9 synthesis

주요 응용

Diallyl phthalate is an important monomer for the production of thermosetting molding compounds, which must have good dimensional stability and electrical properties, and be resistant to heat and solvents. Diallyl phthalate can be polymerized or copolymerized. This usually is done by dissolving the diallyl phthalate monomer in 2- propanol, adding 50% hydrogen peroxide at about 105 ℃, and precipitating the prepolymer from the cooled, viscous solution with excess 2- propanol. Copolymers containing diallyl phthalate are suitable for specialty coating and for embedding, especially in the production of electronic devices. For example, the moisture-sensitive epoxy compounds now used in light-emitting diode (LED) displays can be replaced by stable diallyl phthalate epoxy encapsulating resins. By adding inorganic materials to diallyl phthalate prepolymer compositions, reinforced thermosetting molding compounds can be obtained. Glass cloth or paper can be impregnated with a solution of prepolymer, monomer, and peroxide initiator. After removal of the solvent, the glass cloth or paper is cured to give the desired film-protected material, which is used for decoration, stain-resistant overlays for household articles, and furniture.

일반 설명

Clear pale-yellow liquid. Odorless.

공기와 물의 반응

Incompatible with water and oxygen. Should be stored air tight, with inhibitor, to prevent polymerization reaction .

반응 프로필

Diallyl phthalate can react with oxidizers. Diallyl phthalate can also react with acids and alkalis. Diallyl phthalate is incompatible with water and oxygen.

화재위험

Diallyl phthalate is combustible.

Safety Profile

Suspected carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, intraperitoneal, and subcutaneous routes. An eye irritant. Mutation data reported. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use CO2 or dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS.

Carcinogenicity

In the 103-week study referred to previously, a slight increase in MNCL was seen in female rats treated with 50 or 100 mg/kg/day of DAP. MNCL occurs in F344 control rats at a high incidence; however, the incidence of 51% in female rats at the high dose level was above historical control data for the laboratory (29%). No significant increases in tumor incidences were seen in male rats. Based on this study, DAP was considered to have demonstrated equivocal evidence for carcinogenicity in female F344 rats according to the NTP.
In male and female B6C3F1 mice receiving 300 mg/kg of DAP by gavage for 103 weeks (5 days/week), the incidence of forestomach papillomas was significantly greater than that of controls. Because of the rarity of forestomach papillomas in control B6C3F1 mice and the concomitant observation of dose-related forestomach hyperplasia, the development of these tumors was considered to be test substance related. Compared to controls, a slight increase in the incidence of lymphomas was observed in males receiving 300 mg/kg/day of DAP. Because the increase was not statistically significant compared to historical control data, this effect was not considered to be test substance related.

프탈산디알릴모노머 준비 용품 및 원자재

원자재

준비 용품


프탈산디알릴모노머 공급 업체

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