1,2,3,5-Tetrachlorobenzene

1,2,3,5-Tetrachlorobenzene 구조식 이미지
카스 번호:
634-90-2
상품명:
1,2,3,5-Tetrachlorobenzene
동의어(영문):
1,2,3,5-tcb;1,2,3,5-Tetrachlorob;1,3,4,5-Tetrachlorbenzol;,2,3,5-TETRACHLOROBENZENE;Nicotinamide Impurity 249;1,2,3,5-TETRACHLOROBENZENE;tetrachloro1,2,3,5-benzene;1,2,4,6-tetrachlorobenzene;1,2,3,5-tetrachloro-benzen;1,3,4,5-Tetrachlorobenzene
CBNumber:
CB1395743
분자식:
C6H2Cl4
포뮬러 무게:
215.89
MOL 파일:
634-90-2.mol
MSDS 파일:
SDS

1,2,3,5-Tetrachlorobenzene 속성

녹는점
54.5°C
끓는 점
246°C
밀도
1.5578 (estimate)
증기압
0.07 at 25 °C (extrapolated, Mackay et al., 1982)
굴절률
1.5348 (estimate)
인화점
113 °C
저장 조건
APPROX 4°C
용해도
알코올, 벤젠, 에테르 및 리그로인에 용해됨(Weast, 1986)
색상
흰색에서 거의 흰색
수용성
4.016mg/L(25℃)
BRN
1618864
Henry's Law Constant
58.0 at 25 °C (gas stripping-GC, Shiu and Mackay, 1997)
CAS 데이터베이스
634-90-2(CAS DataBase Reference)
NIST
Benzene, 1,2,3,5-tetrachloro-(634-90-2)
EPA
1,2,3,5-Tetrachlorobenzene (634-90-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,T,F
위험 카페고리 넘버 22-39/23/24/25-23/24/25-11
안전지침서 22-24/25-45-36/37-16-7
유엔번호(UN No.) UN 1230 3/PG 2
WGK 독일 3
RTECS 번호 DB9445000
HS 번호 2903.99.8001
유해 물질 데이터 634-90-2(Hazardous Substances Data)
독성 Acute oral LD50 for rats 1,727 mg/kg (quoted, RTECS, 1985).
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P391 누출물을 모으시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
1
1 0

1,2,3,5-Tetrachlorobenzene MSDS


1,2,3,5-Tetrachlorobenzene

1,2,3,5-Tetrachlorobenzene C화학적 특성, 용도, 생산

정의

ChEBI: A tetrachlorobenzene carrying chloro groups at positions 1, 2, 3 and 5.

일반 설명

White crystals or off-white solid.

공기와 물의 반응

Insoluble in water.

반응 프로필

Simple aromatic halogenated organic compounds, such as 1,2,3,5-Tetrachlorobenzene , are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. 1,2,3,5-Tetrachlorobenzene may react with oxidizers. .

건강위험

ACUTE/CHRONIC HAZARDS: 1,2,3,5-Tetrachlorobenzene may cause irritation on contact.

화재위험

1,2,3,5-Tetrachlorobenzene is probably combustible.

환경귀착

Biological. A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,2,3,5-tetrachlorobenzene to 2,3,4,6-tetrachlorophenol (Ballschiter and Scholz, 1980). The half-life of 1,2,3,5- tetrachlorobenzene in an anaerobic enrichment culture was 1.8 d (Beurskens et al., 1993).
In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,2,3,5- tetrachlorobenzene underwent reductive dechlorination to 1,2,4- and 1,3,5-trichlorobenzene at relative molar yields of 7 and 93%, respectively. The maximum dechlorination rate, based on the recommended Michaelis-Menten model, was 94 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. Irradiation (λ ≥285 nm) of 1,2,3,5-tetrachlorobenzene (1.1–1.2 mM/L) in an acetonitrile-water mixture containing acetone (0.553 mM/L) as a sensitizer gave the following products (% yield): 1,2,3-trichlorobenzene (5.3), 1,2,4-trichlorobenzene (4.9), 1,3,5-trichlorobenzene (49.3), 1,3-dichlorobenzene (1.8), 2,3,4,4′,5,5′,6-heptachlorobiphenyl (1.41), 2,2′,3,4,4′,6,6′- heptachlorobiphenyl (1.10), 2,2′,3,3′,4,5′,6-heptachlorobiphenyl (4.50), four hexachlorobiphenyls (4.69), one pentachlorobiphenyl (0.64), trichloroacetophenone, 1-(trichlorophenyl)-2-propanone, and (trichlorophenyl)acetonitrile (Choudhry and Hutzinger, 1984). Without acetone, the identified photolysis products (% yield) included 1,2,3-trichlorobenzene (trace), 1,2,4-trichlorobenzene (24.3), 1,3,5-trichlorobenzene (11.7), 1,3-dichlorobenzene (0.5), 1,4-dichlorobenzene (3.3), pentachlorobenzene (1.43), 1,2,3,4-tetrachlorobenzene (5.99), two heptachlorobiphenyls (1.40), two hexachlorobiphenyls (<0.01), and one pentachlorobiphenyl (0.75) (Choudhry and Hutzinger, 1984).

Purification Methods

Crystallise it from EtOH. [Beilstein 5 II 157, 5 III 551, 5 IV 668.]

1,2,3,5-Tetrachlorobenzene 준비 용품 및 원자재

원자재

준비 용품


1,2,3,5-Tetrachlorobenzene 공급 업체

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