퍼플루오로헥산

퍼플루오로헥산
퍼플루오로헥산 구조식 이미지
카스 번호:
355-42-0
한글명:
퍼플루오로헥산
동의어(한글):
퍼플루오로헥산
상품명:
Tetradecafluorohexane
동의어(영문):
FC-72;FLUORINERT;TETRADECAFLUOROHEXANE;PFC-51-14;FLUORINERT FC-72;PERFLUOROHEXANES;n-Perfluorohexane;PF5060;Hexane, tetradecafluoro-;PerfL
CBNumber:
CB2743404
분자식:
C6F14
포뮬러 무게:
338.04
MOL 파일:
355-42-0.mol
MSDS 파일:
SDS

퍼플루오로헥산 속성

녹는점
−4 °C(lit.)
끓는 점
58-60 °C(lit.)
밀도
1.669 g/mL at 25 °C(lit.)
증기압
26.5kPa at 25℃
굴절률
n20/D 1.252(lit.)
인화점
56-60°C
물리적 상태
액체
Specific Gravity
1.699
색상
무색의
수용성
물과 섞이지 않습니다.
Merck
14,7157
BRN
1802113
Dielectric constant
1.5700000000000001
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
InChIKey
ZJIJAJXFLBMLCK-UHFFFAOYSA-N
LogP
4.5 at 20℃ and pH7
CAS 데이터베이스
355-42-0(CAS DataBase Reference)
EPA
Perfluorohexane (355-42-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36
유엔번호(UN No.) 2810
WGK 독일 3
RTECS 번호 MO4310000
위험 참고 사항 Irritant
TSCA T
위험 등급 6.1(b)
포장분류 III
HS 번호 29033990
유해 물질 데이터 355-42-0(Hazardous Substances Data)
기존화학 물질 KE-33330
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P273 환경으로 배출하지 마시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
0
0 0

퍼플루오로헥산 C화학적 특성, 용도, 생산

화학적 성질

colourless liquid

용도

Perfluorohexanes is used as a coolant, photosensitizer in fluorous biphasic singlet oxygenation and an inert reaction medium. It is used in the electronic cooling liquid and insulator. It plays a vital role as a reaction medium, especially for photooxidation reactions. Further, it finds application as an ultrasound contrast agent.

주요 응용

Perfluorohexane uses and applications include: dispersant for lubricants, mold release agents, protective coatings; reaction media for polymerizations, purification, separation processes; solvent for removal of halogenated lubricants, oils, greases; carrier for halogenated material; for quick-cooling or freezing foods; heat-transfer fluid.
Because it is biologically inert and chemically stable, perfluorohexane has attracted attention in medicine. Like other fluorocarbons, perfluorohexane dissolves gases, including oxygen from the air, to a higher concentration than ordinary organic solvents. This effect is attributed to the weak intermolecular forces between perfluorohexane molecules, which allows "space" for gas molecules to partition into the liquid. Animals can be submerged in a bath of perfluorohexane without drowning, as there is sufficient oxygen available in the solvent to allow respiration to continue. This effect has led to the experimental use of perfluorohexane in treating burn victims, as their lungs can be filled with either perfluorohexane vapor or in extreme cases liquid perfluorohexane, allowing breathing to continue without the problems normally seen with pulmonary edema that sometimes occur when the inside of the lungs have been burnt e.g. by inhalation of hot smoke.

일반 설명

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Purification Methods

Purify the fluorohexane by fractional freezing. The methods described for perfluoroheptane should be applicable here. [Beilstein 1 IV 348.]

퍼플루오로헥산 준비 용품 및 원자재

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