Allyltriphenylphosphonium bromide
|
|
Allyltriphenylphosphonium bromide 속성
- 녹는점
- 222-225 °C (lit.)
- 저장 조건
- Sealed in dry,Room Temperature
- 물리적 상태
- 가루
- 색상
- 하얀색
- 수용성
- 물에서 분해되다
- 감도
- Hygroscopic
- BRN
- 3579053
- InChI
- InChI=1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
- InChIKey
- FWYKRJUVEOBFGH-UHFFFAOYSA-M
- SMILES
- [P+](CC=C)(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.[Br-]
- CAS 데이터베이스
- 1560-54-9(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xi | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 36/37/38 | ||
| 안전지침서 | 26-37/39 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | TA1843000 | ||
| HS 번호 | 29310095 | ||
| 독성 | mouse,LD50,intravenous,22mg/kg (22mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01708, |
Allyltriphenylphosphonium bromide C화학적 특성, 용도, 생산
화학적 성질
white crystalline powder용도
Allyltriphenylphosphonium bromide is used for the first time in the preparation of DES. It has been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A. It can be used in witting olefination of aldehydes for preparation of conjugated dienes.제조 방법
Allyltriphenylphosphonium bromide was synthesized from the reaction of triphenylphosphine and allyl bromide in dry toluene.주요 응용
Reactant for:Preparation of a diol and carbamate chemistry library for common functional groups
Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
Alkene addition of frustrated Lewis pairs
Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
Wittig olefination of aldehydes for preparation of conjugated dienes
Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes.
Methyl 3-(buta-1,3-dienyl)benzoate
1-(Buta-1,3-dienyl)-4-(trifluoromethyl)benzene
1-(Buta-1,3-dienyl)-2-chlorobenzene
1-Bromo-4-(buta-1,3-dienyl)benzene
Buta-1,3-dienylbenzene
Allyltriphenylphosphonium bromide 준비 용품 및 원자재
원자재
준비 용품
Allyltriphenylphosphonium bromide 공급 업체
글로벌( 211)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| TCI Europe | 320-37350700 |
sales@tcieurope.eu | Europe | 23680 | 75 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32686 | 60 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 |
sales@chemdad.com | China | 39916 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 |
sales@alchempharmtech.com | United States | 63711 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49391 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | 18192627656 |
1012@dideu.com | China | 2409 | 58 |
| SIMAGCHEM CORP | +86-13806087780 |
sale@simagchem.com | China | 17367 | 58 |
| Hubei Ipure Biology Co., Ltd | +8613367258412 |
ada@ipurechemical.com | China | 10326 | 58 |
Allyltriphenylphosphonium bromide 관련 검색:
트리페닐포스핀 에티듐 브로마이드 메틸트리페닐포스포늄브로마이드 브롬화알릴 브롬화테트라-n-프로필암모늄 브로민산나트륨 테트라 키스 (트리 페닐 포스 핀) 팔라듐 (0) 디미듐 브로마이드 테트라페닐 인 브로마이드 트리페닐포스핀 옥사이드 트리스(트리페닐포스핀)로듐(I) 염화물 브롬화 메틸
Allyl triphenylphosphonium chloride
TETRAPHENYLPHOSPHINE IMIDE
Rocuronium bromide
Vecuronium bromide
Triphenylphosphine hydrobromide
ALLYLTRIPHENYLTIN