구리벤조에이트

구리벤조에이트
구리벤조에이트 구조식 이미지
카스 번호:
533-01-7
한글명:
구리벤조에이트
동의어(한글):
구리벤조에이트
상품명:
Copper benzoate
동의어(영문):
COPPER BENZOATE;CUPRIC BENZOATE;cupric dibenzoate;copper dibenzoate;COPPER (II) BENZOATE;Copper Benzoate Powder;Cupric benzoate monohydrate;benzoicacid,copper(2++)salt;BENZOIC ACID COPPER (II) SALT;Dibenzoic acid copper(II) salt
CBNumber:
CB5718108
분자식:
C14H10CuO4
포뮬러 무게:
305.77
MOL 파일:
533-01-7.mol

구리벤조에이트 속성

안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
그림문자(GHS):
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:

구리벤조에이트 C화학적 특성, 용도, 생산

개요

Copper benzoate is the chemical compound with the formula Cu(C6H5CO2)2. This coordination complex is derived from the cupric ion and the conjugate base of benzoic acid. Because copper emits blue in a flame, this salt has found some use as a source of blue light in fireworks.

화학적 성질

Blue, crystalline powder; odorless.Slightly soluble in cold water, acids, and alcohol.

물리적 성질

Copper (II) benzoates exists in at least two structural forms , depending on the degree of hydration. As for copper (II) acetate , the benzoate adopts a "Chinese lantern" structure, wherein a pair of copper centers are linked by four bridging carboxylate ligands. Typically one site on each copper center is occupied by water, which can be replaced by other ligands . A hydrated form is also known, wherein each Cu (II) center is bound to four water ligands and benzoate .

용도

Cupric benzoate monohydrate (cas# 533-01-7) is used as a catalyst in the preparation of positive resist compositions comprising sulfonium compounds as acid diffusion inhibitors for high resolution and minimal line edge roughness.

제조 방법

In laboratory, copper benzoate can be made by combining aqueous solutions of potassium benzoate with copper sulfate. Copper benzoate precipitates as a pale blue solid :
2 C6H5COOK + CuSO4 →Cu(C6H5COO)2 + K2SO4
The primary use of this of this compound is in production of blue flame in fireworks. Copper benzoate made from sodium benzoate for use in fireworks may result in strong yellow dilution of the flame unless the precipitate is carefully washed to remove sodium ion (which emits brightly yello). Emission from potassium does not complicate the emission spectrum.

Purification Methods

Recrystallise it from hot water. Its solubility in EtOH/*C6H6 (90%) at 25o is 0.1%. [Crawford & Stewart J Chem Soc 228, 289 1953, Beilstein 9 H 84, 9 I 60, 9 III 376, 9 IV 280.]

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