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사이클로헥사논옥심

사이클로헥사논옥심 구조식 이미지

카스 번호:: 100-64-1

한글명:: 사이클로헥사논옥심

동의어(한글):: (하이드록시아미노)시클로헥산;사이클로헥사논옥심;사이클로헥사논옥심;시클로헥사논옥심

상품명:: Cyclohexanone oxime

동의어(영문):: CHO;Antioxidant D;Cyclohexanonoxim;AKOS BBS-00004405;Cyclohexane oxime;Cyclohexanon-oxime;Cylohexanone oxime;CYCLOHEXANONE OXIME;CCYLOHEXANONE OXIME;Cyclohexanone oxium

CBNumber:: CB8487050

분자식:: C6H11NO

포뮬러 무게:: 113.16

MOL 파일:: 100-64-1.mol

MSDS 파일:: SDS

속성

안전

MSDS

용도

공급 업체 336

사이클로헥사논옥심 속성

녹는점: 86-89 °C (lit.)

끓는 점: 206-210 °C (lit.)

밀도: 1.0125 (rough estimate)

증기압: 1.78Pa at 20℃

굴절률: 1.4860 (estimate)

인화점: 90 °C

저장 조건: Store below +30°C.

용해도: 17.7g/L

물리적 상태: 결정질 분말, 결정 또는 덩어리

산도 계수 (pKa): 12.42±0.20(Predicted)

색상: 황백색에서 베이지색 갈색까지

수용성: 20°C에서 <0.1g/100mL

BRN: 1616769

Dielectric constant: 3.0（89℃）

안정성: 안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다. 고온에서 발연황산과 격렬하게 반응함.

InChIKey: VEZUQRBDRNJBJY-UHFFFAOYSA-N

LogP: 1.265 at 25℃

CAS 데이터베이스: 100-64-1(CAS DataBase Reference)

NIST: Cyclohexanone, oxime(100-64-1)

EPA: Cyclohexanone oxime (100-64-1)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	Xn
위험 카페고리 넘버	22
안전지침서	36/37/39
WGK 독일	1
RTECS 번호	GW1925000
TSCA	Yes
HS 번호	29280090
유해 물질 데이터	100-64-1(Hazardous Substances Data)

그림문자(GHS):

신호 어:

Warning

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	그림 문자	P- 코드
H302	삼키면 유해함	급성 독성 물질 - 경구	구분 4	경고		P264, P270, P301+P312, P330, P501

예방조치문구:

NFPA 704

	2
2		0

사이클로헥사논옥심 MSDS

Antioxidant D

사이클로헥사논옥심 C화학적 특성, 용도, 생산

화학적 성질

Cyclohexanone oxime, a white crystalline solid, has a molecular weight of 113.16 and a melting point of 90 C. It is soluble in water and ethanol (Lide, 1992). This colorless solid is an important intermediate in the production of nylon 6, a widely used polymer. Cyclohexanone oxime is produced by the condensation of cyclohexanone with hydroxylamine sulfate or hydroxylamine phosphate (Fisher and Cresentini, 1985).

용도

Cyclohexanone oxime is used in a wide variety of industrial applications. Primarily, it is used as a captive intermediate in the synthesis of caprolactam, which is polymerized in the production of polycaprolactam (Nylon-6) fibers and plastics (Fisher and Cresentini, 1985; NCI, 1985). The annual U.S. caprolactam production is over 500,000 tons (NCI, 1985). Approximately 90% of the monomer is used to produce fibers for clothing, carpets, home furnishings, and tire cording. The remaining 10% is used to produce nylon resins for food packaging film, extrusion compounds for bristle filaments and wire coatings, and molded plastics for automobiles and appliances (NCI, 1985). Cyclohexanone oxime is also thought to be an intermediate in the oxidative metabolism of sodium cyclamate, an artificial sweetener (Unger and McMahon, 1981).

일반 설명

Prisms, liquid or light tan crystalline solid.

공기와 물의 반응

Insoluble in water.

반응 프로필

Cyclohexanone oxime reacts violently with fuming sulfuric acid at temperatures > 302° F. . Several explosions or violent decompositions have occurred during distillation of aldooximes, which may be attributable to the formation of peroxides of various types. This is especially the case in the presence of acid, Chem. Eng. News, 1974, 52(35), 3. A nickel catalyzed aldoxime rearrangement to an amide, went out of control after changing the solvent employed, J. Loss Prev., 1993, 6(2), 69.

건강위험

ACUTE/CHRONIC HAZARDS: When heated to decomposition Cyclohexanone oxime emits toxic fumes of nitrogen oxides.

화재위험

Flash point data for Cyclohexanone oxime are not available; however, Cyclohexanone oxime is probably combustible.

Purification Methods

Crystallise the oxime from water or pet ether (b 60-80o). [Bousquet Org Synth Coll Vol II 313 1943, Beilstein 7 III 32, 7 IV 21.]

사이클로헥사논옥심 준비 용품 및 원자재

원자재

카프로락탐 Cyclohexanimine 트리메틸(시클로헥실옥시)실란 2H-Pyran, 2-(cyclohexyloxy)tetrahydro- 1-Amino-1-hydroperoxycyclohexane N-CYCLOHEXYLHYDROXYLAMINE Cyclohexanone, 2-cyclohexylidenehydrazone 헥사하이드로니트로벤젠 노보넨모노머

준비 용품

3-Amino-2-azepanone 카프로락탐 황산암모늄 사이클로헥사논

사이클로헥사논옥심 공급 업체

글로벌( 336)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12470	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	6011	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21687	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21149	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12822	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34571	58
ANHUI WITOP BIOTECH CO., LTD	+8615255079626	eric@witopchemical.com	China	23556	58

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