1,1'-아조비스-(시클로헥산-1-카르보니트릴)
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1,1'-아조비스-(시클로헥산-1-카르보니트릴) 속성
- 녹는점
- 114-118 °C(lit.)
- 끓는 점
- 423.9±38.0 °C(Predicted)
- 밀도
- 1.13±0.1 g/cm3(Predicted)
- 증기압
- 0-0.001Pa at 20-25℃
- 저장 조건
- 2-8°C
- 물리적 상태
- Solid:crystalline
- BRN
- 960744
- 안정성
- 안정적이지만 약 114C 이상에서는 발열 분해됩니다.
- LogP
- 3.256 at 25℃ and pH5-6
- CAS 데이터베이스
- 2094-98-6(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | F,Xi | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 11-36/37/38 | ||
| 안전지침서 | 26 | ||
| 유엔번호(UN No.) | UN 3226 4.1 | ||
| WGK 독일 | 3 | ||
| F 고인화성물질 | 4.9 | ||
| 위험 등급 | 4.1 | ||
| 포장분류 | II | ||
| 기존화학 물질 | 2004-3-2905 |
| 그림문자(GHS): |
 
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| 신호 어: | Danger | |||||||||||||||||||||||||||||||||||
| 유해·위험 문구: |
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| 예방조치문구: |
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1,1'-아조비스-(시클로헥산-1-카르보니트릴) C화학적 특성, 용도, 생산
화학적 성질
faintly beige crystalline powder용도
A more efficient radical initiator than AIBN has been employed to initiate primary radical reactions.일반 설명
A white to light colored solid substance. Insoluble in water and more dense that water. May cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. If exposed to high temperatures or flames 1,1'-Azobis(cyanocyclohexane) may ignite and burn with an intense flame. Dust may form an explosive mixture in air.공기와 물의 반응
Dust may form an explosive mixture in air. Insoluble in water.반응 프로필
Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. May be ignited by heat, sparks or flames. 1,1'-Azobis(cyanocyclohexane) is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.건강위험
Fire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.화재위험
Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished.Purification Methods
Purify the nitrile by dissolving it in boiling 95%EOH as rapidly as possible, cool overnight at 0o, filter, wash with a little EtOH and dry it in a vacuum desiccator over CaCl2. Note that prolonged heating >80o causes decomposition. Recrystallise it from EtOH. It should be regarded as potentially explosive. It is a radical initiator. [Overberger et al. Org Synth Coll Vol IV 66 1963, Beilstein 16 II 97.]1,1'-아조비스-(시클로헥산-1-카르보니트릴) 준비 용품 및 원자재
원자재
준비 용품
1,1'-아조비스-(시클로헥산-1-카르보니트릴) 공급 업체
글로벌( 85)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21688 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32686 | 60 |
| Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 |
info@konochemical.com | China | 2995 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49391 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; |
factory@coreychem.com | China | 29826 | 58 |
| SIMAGCHEM CORP | +86-13806087780 |
sale@simagchem.com | China | 17367 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 |
sales@tnjchem.com | China | 34572 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 |
cherry@crovellbio.com | China | 18444 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 |
market18@leapchem.com | China | 43348 | 58 |
1,1'-아조비스-(시클로헥산-1-카르보니트릴) 관련 검색:
메틸사이클로헥산 페닐사이클로헥세인 사이클로헥세인 사이클로헥센옥사이드 에틸사이클로헥산 헥사하이드로니트로벤젠 클로로시클로헥산 2,2'아조디-2-메틸부티로니트릴 아조비스이소부티로니트릴 1,1'-아조비스-(시클로헥산-1-카르보니트릴)
Cyclohexanecarbonitrile
AZO-TERT-BUTANE
2-AMINO-2-METHYL-PROPIONITRILE
1-AMINO-1-METHYLCYCLOHEXANE
1-amino-1-cyanocyclohexane
1,1'-AZODICYCLOHEXANE CARBONITRILE
1,4'-Azobis(cyclohexanecarbonitrile)
2-METHYLHEXANENITRILE