초산 이소부틸

초산 이소부틸
초산 이소부틸 구조식 이미지
카스 번호:
110-19-0
한글명:
초산 이소부틸
동의어(한글):
아이소뷰틸아세테이트;아세트산아이소뷰틸;초산이소부틸;이소부틸아세테이트(I.B.A);아세트산아이소뷰틸;아이소부틸아세테이트;초산이소부틸;아이소뷰틸 아세테이트;2-메틸-1-프로필 아세트산;2-메틸프로필 아세트산;베타-메틸프로필 에타노에이트;아세트산 아이소뷰틸;아세트산, 2-메틸프로필 에스터;아세트산, 아아이소뷰틸 에스터
상품명:
Isobutyl acetate
동의어(영문):
2-METHYLPROPYL ACETATE;Acetic acid, 2-methylpropyl ester;i-Butyl acetate;ISOBUTYL ACETATE(SG);2-Methylpropyl ethanoate;ACETIC ACID ISOBUTYL ESTER;FEMA 2175;99.8% (GC);Citrate-d4;Acetic acid is
CBNumber:
CB8852805
분자식:
C6H12O2
포뮬러 무게:
116.16
MOL 파일:
110-19-0.mol
MSDS 파일:
SDS

초산 이소부틸 속성

녹는점
-99 °C (lit.)
끓는 점
115-117 °C (lit.)
밀도
0.867 g/mL at 25 °C (lit.)
증기 밀도
>4 (vs air)
증기압
15 mm Hg ( 20 °C)
FEMA
2175 | ISOBUTYL ACETATE
굴절률
n20/D 1.39(lit.)
인화점
71 °F
저장 조건
Store below +30°C.
용해도
물: 20°C에서 용해성5.6g/L
물리적 상태
액체
색상
투명한
수소이온지수(pH)
5 (4g/l, H2O, 20℃)
냄새
낮은 농도에서는 기분 좋은 과일 향이 나고, 높은 농도에서는 불쾌합니다. 온화하고 특징적인 에스테르; 비잔류.
pH 범위
7
?? ??
과일 같은
Odor Threshold
0.008ppm
폭발한계
2.4-10.5%(V)
수용성
7g/L(20℃)
Merck
14,5130
JECFA Number
137
BRN
1741909
Henry's Law Constant
(x 10-4 atm?m3/mol): 4.85 at 25 °C (approximate - calculated from water solubility and vapor pressure)
노출 한도
TLV-TWA 150 ppm (~700 mg/m3) (ACGIH, MSHA, and OSHA); IDLH 7500 ppm (NIOSH).
Dielectric constant
5.6(20℃)
LogP
2.3 at 25℃
CAS 데이터베이스
110-19-0(CAS DataBase Reference)
NIST
Isobutyl acetate(110-19-0)
EPA
Isobutyl acetate (110-19-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F
위험 카페고리 넘버 11-66
안전지침서 16-23-25-29-33
유엔번호(UN No.) UN 1213 3/PG 2
WGK 독일 1
RTECS 번호 AI4025000
자연 발화 온도 793 °F
TSCA Yes
HS 번호 2915 39 00
위험 등급 3
포장분류 II
유해 물질 데이터 110-19-0(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 13400 mg/kg LD50 dermal Rabbit > 17400 mg/kg
IDLA 1,300 ppm [10% LEL]
기존화학 물질 KE-00055
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H336 졸음 또는 현기증을 일으킬 수 있음 특정표적장기 독성 물질(1회 노출);마취작용 구분 3 경고 P261, P271, P304+P340, P312,P403+P233, P405, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P241 폭발 방지용 장비[전기적/환기/조명/...]을(를) 사용하시오.
P242 스파크가 발생하지 않는 도구를 사용하시오
P243 정전기 방지 조치를 취하시오.
NFPA 704
3
1 0

초산 이소부틸 C화학적 특성, 용도, 생산

용도

1. 코팅
2. 고분자 도료
3. 업자
4. 접착제
5. 향기 솔벤트
6. 추출 용매
7. 이소시아네이트 아이 커
8. 화장품 / 퍼스널 케어 용매

포장, 보관 및 운송

부적합 물질로부터 차갑고 건조하고 통풍이 잘되는 곳에 보관하십시오.

개요

Isobutyl acetate has a fruity (currant-pear), floral (hyacinth-rose) odor and a characteristic ether-like, slightly bitter flavor. May be prepared by direct esterification of isobutyl alcohol with acetic acid.

화학적 성질

Isobutyl acetate is a colorless liquid with a fruit flavor. Isobutyl acetate is moisture sensitive, incompatible with ignition sources, moisture, excess heat, strong oxidizing agents, and strong bases; on decomposition, it releases carbon monoxide and carbon dioxide. It is used for nitrification fiber and paint solvents, chemical reagents, and modulation spices

물리적 성질

Colorless liquid with a fruity odor. Experimentally determined detection and recognition odor threshold concentrations were 1.7 mg/m3 (360 ppbv) and 2.4 mg/m3 (510 ppbv), respectively (Hellman and Small, 1974).

출처

Reported found in, apple, apricot, banana, currants, guava, grapes, melon, pear, blackcurrant, papaya, pineapple, strawberry, vinegar, wheat bread, Parmesan and Gruyere cheese, beef fat, beer, cognac, rum, cider, whiskies, sherry, grape wines, port, olive, cocoa, passion fruit, plum, starfruit, bantu beer, plum and grape brandy, mango, tamarind, apple brandy, figs, plum wine, litchi, sake, nectarine, naranjilla fruit, Cape gooseberry and Roman chamomile oil.

용도

Isobutyl Acetate is a flavoring agent that is a clear colorless liquid with a fruity odor resembling banana when diluted. it is soluble in alcohol, propylene glycol, most fixed oils, and mineral oil, and slightly soluble in water. it is obtained by synthesis.

제조 방법

By direct esterification of isobutyl alcohol with acetic acid.

생산 방법

Isobutyl acetate may be made from methyl isobutyl ketone. It may also be made by treating isobutanol with acetic acid in the presence of catalysts. The Tischenko reaction of acetaldehyde with isobutyraldehyde yields a mixture of isobutyl acetate with ethyl acetate and isobutyl isobutyrate.

정의

ChEBI: The acetate ester of isobutanol.

일반 설명

A clear colorless liquid with a fruity odor. Flash point 64°F. Less dense than water (6.2 lb / gal) and insoluble in water. Vapors are heavier than air .

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

Isobutyl acetate reacts exothermically with acids to give alcohols and other acids. May react sufficiently exothermically with strong oxidizing acids to ignite the reaction products. Reactions with bases also generate heat. Combination with strong reducing agents (alkali metals and hydrides) generates flammable hydrogen.

위험도

Flammable, dangerous fire risk.

건강위험

Isobutyl acetate is more toxic but less of anirritant than n-butyl acetate. The toxic symp toms include headache, drowsiness, irritationof upper respiratory tract, and anesthesia.A 4-hour exposure to 8000 ppm was lethalto rats. It produced mild to moderate irri tation on rabbits’ skin. The irritation ineyes was also mild to moderate. The LD50oral value in rabbit is within the range4800 mg/kg.

화재위험

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

화학 반응

Reactivity with Water No reaction; Reactivity with Common Materials: Softens and dissolves many types of plastics; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

잠재적 노출

n-Butyl acetate is an important solvent in the production of lacquers, leather and airplane dopes, and perfumes. It is used as a solvent and gasoline additive. sec-Butyl acetate is used as a widely used solvent for nitrocellulose, nail enamels and many different purposes. tert-Butyl acetate is common industrial solvent used in the making of lacquers, artificial leather, airplane dope, perfume; and as a food additive. Isobutyl acetate is used as a solvent and in perfumes and artificial flavoring materials

환경귀착

Chemical/Physical. Slowly hydrolyzes in water forming 2-methylpropanol and acetic acid.
At an influent concentration of 1,000 mg/L, treatment with GAC resulted in an effluent concentration of 180 mg/L. The adsorbability of the carbon used was 164 mg/g carbon (Guisti et al., 1974).

운송 방법

UN1123 Butyl acetates, Hazard Class: 3; Labels: 3—Flammable liquid.

비 호환성

All butyl acetates are incompatible with nitrates, strong oxidizers; strong alkalies; strong acids. Butyl acetates may form explosive mixture with air; reacts with water, on standing, to form acetic acid and n-butyl alcohol. Violent reaction with strong oxidizers and potassium-tert-butoxide. Dissolves rubber, many plastics, resins and some coatings. May accumulate static electrical charges, and may cause ignition of its vapors

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

초산 이소부틸 준비 용품 및 원자재

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