벤조퓨란

벤조퓨란
벤조퓨란 구조식 이미지
카스 번호:
271-89-6
한글명:
벤조퓨란
동의어(한글):
2,3-벤조퓨란;벤조퓨란;벤조푸란
상품명:
Benzofuran
동의어(영문):
Coumarone;2,3-BENZOFURAN;1-BENZOFURAN;CUMARONE;BENZO[B]FURAN;BENZOFURANE;Cumaron;coumaron;1-oxidene;BENZOFURAN
CBNumber:
CB8853413
분자식:
C8H6O
포뮬러 무게:
118.14
MOL 파일:
271-89-6.mol
MSDS 파일:
SDS

벤조퓨란 속성

녹는점
<-18℃
끓는 점
173-175 °C(lit.)
밀도
1.095 g/mL at 20 °C(lit.)
굴절률
n20/D 1.567
인화점
133 °F
저장 조건
2-8°C
용해도
디클로로메탄에 용해됨
산도 계수 (pKa)
33.2
물리적 상태
결정질 분말 또는 결정
색상
노란색에서 녹색, 황갈색
수용성
불용성
Merck
14,1088
BRN
107704
LogP
2.670
CAS 데이터베이스
271-89-6(CAS DataBase Reference)
IARC
2B (Vol. 63) 1995
NIST
Benzofuran(271-89-6)
EPA
Benzofuran (271-89-6)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn,Xi
위험 카페고리 넘버 40-52-10
안전지침서 36/37-16
유엔번호(UN No.) UN 1993 3/PG 3
WGK 독일 3
RTECS 번호 DF6423800
F 고인화성물질 10-23
위험 참고 사항 Irritant
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 29329900
유해 물질 데이터 271-89-6(Hazardous Substances Data)
독성 Isolated from coal oil and used in the manufacture of coumarone-indene resin. This resin is used in paints, glue, etc. and is allowed in food packaging. Little is known about the toxicity of benzofuran to humans but acute toxicity in experimental animals involves liver and kidney failure. Chronic toxicity to animals involves damage to the liver, kidneys, lungs, and stomach. Lifetime administration (oral administration) caused cancer in both rats and mice.
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
NFPA 704
2
0 0

벤조퓨란 C화학적 특성, 용도, 생산

화학적 성질

2,3-Benzofuran is a colorless, sweet-smelling, oily liquid made by processing coal into coal oil. It may also be formed during other uses of coal or oil. 2,3-Benzofuran is not used for any commercial purposes, but the part of the coal oil that contains 2,3-benzofuran is made into a plastic called coumarone-indene resin. This resin resists corrosion and is used to make paints and varnishes. The resin also provides water resistance and is used in coatings on paper products and fabrics. It is used as an adhesive in food containers and some asphalt fl oor tiles. The resin has been approved for use in food packages and as a coating on citrus fruits. We do not know how often the resin is used or whether any 2,3-benzofuran in the coating or packaging gets into the food. 2,3-Benzofuran may enter the air, water, and soil during its manufacture, use, or storage at hazardous waste sites. Breathing contaminated air or touching the chemical in the workplace is the source of human exposure.

용도

manufacture of coumarone-indene resins.

정의

A bicyclic ring compound derived from coal tar naphtha, the parent substance of coumarone-indene resins.

일반 설명

Clear oily yellow liquid with an aromatic odor.

공기와 물의 반응

Highly flammable. May be sensitive to prolonged exposure to air. Very slightly water soluble.

반응 프로필

Benzofuran slowly polymerizes on standing. Benzofuran may be sensitive to prolonged exposure to air. Benzofuran is polymerized by H2SO4.

위험도

Possible carcinogen.

건강위험

ACUTE/CHRONIC HAZARDS: When heated to decomposition Benzofuran emits acrid and irritating smoke and fumes.

화재위험

Benzofuran is combustible.

Carcinogenicity

Benzofuran was not mutagenic in bacterial assays but did cause chromosomal aberrations and sister chromatid exchanges in cultured rodent cells.

Purification Methods

Benzofuran is steam distilled, dissolved in Et2O, washed with 5% aqueous NaOH, saturated NaCl, dried (Na2SO4), evaporated and redistilled. UV: max 245, 275, 282nm (log 4.08, 3.45, 3.48). The picrate has m 102-103o. [Burgstahler & Worden Org Synth Coll Vol V 251 1973, NMR: Black & Heffernan Aust J Chem 18 353 1965, Beilstein 17/2 V 3.]

벤조퓨란 준비 용품 및 원자재

원자재

준비 용품


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