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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

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Products Intro: Product Name:Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
CAS:742103-27-1
Purity:95% Min. Package:5g, 10g, 100g; 500g; 1kg; 25kg
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Products Intro: Product Name: Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
CAS:742103-27-1
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Products Intro: Product Name:Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
CAS:742103-27-1
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Products Intro: Product Name:Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine
CAS:742103-27-1
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Products Intro: CAS:742103-27-1
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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Basic information
Reactions
Product Name:Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
Synonyms:Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP;cBRIDP(regR);Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine;cBRIDP®;Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)-;cBRIDP[R];Bis-(1,1-dimethylethyl)-(1-methyl-2,2-diphenylcyclopropyl)-phosphine;Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine
CAS:742103-27-1
MF:C24H33P
MW:352.49
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine;organophosphine ligand
Mol File:742103-27-1.mol
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Structure
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Chemical Properties
Melting point 87-91°C
Boiling point 427.3±45.0 °C(Predicted)
form solid
color white to pale yellow
Sensitive air sensitive, store cold
CAS DataBase Reference742103-27-1
Safety Information
WGK Germany 3
HS Code 2931499090
MSDS Information
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Usage And Synthesis
Reactions
  1. Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
  2. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
  3. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction. 
Reactions of 742103-27-1
UsesLigand for greener Buchwald-Hartwig coupling in TPGS-750-M.
General DescriptionThis product has been enhanced for catalytic efficiency.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Preparation Products And Raw materials
Tag:Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP(742103-27-1) Related Product Information
Dicyclohexyl(2,2-diphenyl-1-methylcyclopropyl)phosphine Cy-cBRIDP 2-(Dicyclohexylphosphino)-1,1-diphenyl-1-propene, Dicyclohexyl(1-methyl-2,2-diphenylvinyl)phosphine 1.1'-Binaphthyl-2.2'-diphemyl phosphine Tri-tert-butylphosphine DI-T-BUTYLNEOPENTYLPHOSPHINE, MIN. 95 Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP