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SODIUM SULFATE DECAHYDRATE

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CAS:7727-73-3
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Purity:99% Package:25KG;5KG;1KG

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  • SODIUM SULFATE DECAHYDRATE
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  • $50.00 / 1KG
  • 2023-12-23
  • CAS:7727-73-3
  • Min. Order: 1KG
  • Purity: 99%
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SODIUM SULFATE DECAHYDRATE Basic information
Occurrence Physical Properties Production
Product Name:SODIUM SULFATE DECAHYDRATE
Synonyms:GLAUBER'S SALT;NATRII SULFAS DECAHYDRICUS;SODIUM SULPHATE 10-HYDRATE;SODIUM SULFATE, 10-HYDRATE;SODIUM SULFATE DECAHYDRATE;SODIUM SULFATE DODECAHYDRATE;SODIUM SULFATE, HYDROUS;sopdiumsulfatedecahydrate
CAS:7727-73-3
MF:H20Na2O14S
MW:322.19
EINECS:616-445-4
Product Categories:
Mol File:7727-73-3.mol
SODIUM SULFATE DECAHYDRATE Structure
SODIUM SULFATE DECAHYDRATE Chemical Properties
Melting point 32-38°C
density 1.46 g/mL at 25 °C(lit.)
storage temp. Store at +15°C to +25°C.
solubility H2O: 1 M at 20 °C, clear, colorless
form Solid
color White
Specific Gravity1.46
PH5.2-8.0 (50g/l, H2O, 25℃)(anhydrous substance)
Water Solubility Soluble in water and glycerin. Insoluble in ethanol and methanol.
λmaxλ: 260 nm Amax: ≤0.025
λ: 280 nm Amax: ≤0.021
Merck 14,8680
Stability:Stable. Incompatible with strong acids, aluminium, magnesium.
InChIKeyRSIJVJUOQBWMIM-UHFFFAOYSA-L
LogP-1.031 (est)
CAS DataBase Reference7727-73-3(CAS DataBase Reference)
EPA Substance Registry SystemDisodium sulfate decahydrate (7727-73-3)
Safety Information
Safety Statements 24/25
WGK Germany 1
TSCA Yes
HS Code 28331900
MSDS Information
ProviderLanguage
SigmaAldrich English
SODIUM SULFATE DECAHYDRATE Usage And Synthesis
OccurrenceSodium sulfate occurs in nature as the minerals mirabilite and thenardite. While thenardite is the anhydrous form of Na2SO4, mirabilite is a naturallyoccurring decahydrate, Na2SO4•10H2O.
Sodium sulfate is one of the most important sodium salts. The decahydrate,commonly known as the Glauber’s salt, was first prepared by Johann Glauber in the seventeenth century as a by-product in making hydrochloric acid from sulfuric acid and sodium chloride.
Physical PropertiesAnhydrous sodium sulfate is a white crystalline powder; orthorhombic or hexagonal structure; hygroscopic; refractive index 1.468; hardness 2.8 Mohs; density 2.664 g/cm3; melts at 884°C; soluble in water, insoluble in ethanol.
The decahydrate consists of colorless monoclinic crystals; refractive index 1.394; hardness 1.8 Mohs; density 1.4 6g/cm3; decomposes at 32°C; soluble in water; insoluble in ethanol.
ProductionSodium sulfate is mined from its natural mineral deposits and subjected to purification. Sodium sulfate is synthesized by the Mannheim process or Hargreaves process. Manheim’s process is based on Glauber’s reaction between sulfuric acid and sodium chloride:
2NaCl + H2SO4 → Na2SO4 + 2HCl↑
The process was devised by Johann Glauber to produce hydrochloric acid. Sodium sulfate is isolated from the solution by fractional crystallization. Hargreaves’ process also was developed to produce hydrochloric acid. It is a variation of Mannheim’s method. In this method, sulfur dioxide is used instead of sulfuric acid. The reaction is as follows:
4NaCl + 2SO2 + O2 + 2H2O → 2Na2SO4 + 4HCl↑
Sodium sulfate also is obtained as a byproduct of manufacturing phenol by caustic fusion.
Chemical PropertiesWhite or almost white, crystalline powder or colourless, transparent crystals.
UsesSodium sulfate decahydrate may be used to deepen the color while dyeing cotton fabrics.6
UsesSodium sulfate decahydrate is used as a laboratory reagent to precipitate protein. It is largely used as filler in powdered home laundry detergents. It facilitates in leveling, reducing negative charges on fibers, thereby allows dye to penetrate evenly. It avoids the corrosion of stainless steel vessels used in dyeing. It is also used as a laxative and effectively replaces the drug paracetamol in the body.
UsesSodium sulfate decahydrate is used in manufacturing paper pulp by the Kraft Process. Other uses are in manufacturing glass and ultramarine; in dyeing and printing textiles; as a filler in synthetic detergents; and for standardizing dyes. A major use of anhydrous sodium sulfate is as an agent to remove water from organic solvents and their extracts for organic synthesis and instrumental analysis. Sodium sulfate decahydrate is a common laboratory reagent. Also, it is used to prepare other sodium salts.
DefinitionChEBI: Sodium sulfate decahydrate is a hydrate. It has a role as a cathartic. It contains a sodium sulfate.
General DescriptionSodium sulfate decahydrate (Glauber′s salt, mirabilite, Na2SO4·10H2O) is the decahydrate salt of sodium sulfate. Its crystal structure has been investigated by single-crystal neutron diffraction studies. Its crystallization enthalpy has been evaluated. It can be synthesized by reacting MnSO4, thiophene-2,5-dicarboxylic acid and sodium glutamate.
Purification MethodsCrystallise sodium sulfate from water at 30o (1.1mL/g) by cooling to 0o. It becomes anhydrous at 32o.
Tag:SODIUM SULFATE DECAHYDRATE(7727-73-3) Related Product Information
Aluminum sulfate Phenylhydrazine sulfate Calcium sulfate dihydrate Barite Sodium hydroxide sodium hexametaphosphate Rutile Barium sulfate Artinite Cupric carbonate basic COBALT(III) OXIDE BLACK Zinc sulfate heptahydrate FERROUS SULFATE Aluminum ammonium sulfate Sodium oxide Tetradecylmagnesium chloride SODIUM SULFIDE PENTAHYDRATE SODIUM SULFATE Sodium Sulphate Decahydrate