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| | DoPAT Chemical Properties |
| Melting point | 78-82℃ | | Boiling point | 499.5±24.0 °C(Predicted) | | density | 1.093±0.06 g/cm3(Predicted) | | storage temp. | 2-8°C | | form | powder or crystals | | pka | 2.93±0.10(Predicted) | | InChI | InChI=1S/C16H30O2S3/c1-3-4-5-6-7-8-9-10-11-12-13-20-16(19)21-14(2)15(17)18/h14H,3-13H2,1-2H3,(H,17,18) | | InChIKey | CFCFZJHCTNKHGJ-UHFFFAOYSA-N | | SMILES | C(O)(=O)C(SC(SCCCCCCCCCCCC)=S)C |
| Hazard Codes | F | | Risk Statements | 10 | | Safety Statements | 15-16 | | WGK Germany | 3 |
| | DoPAT Usage And Synthesis |
| Definition |
2-(Dodecylthiocarbonothioylthio)propionic acid (DoPAT) is a trithiocarbonate reversible addition–fragmentation chain transfer (RAFT) agent. DADMAC was polymerized in aqueous solution employing 2,2′-azobis(2-methylpropionamidine)-dihydrochloride as the free-radical initiator and DoPAT as the controlling RAFT agent. 2-(Dodecylthiocarbonothioylthio)propionic acid could only be activated under blue light[1-2].
| | General Description | Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table. | | References |
[1] James P. Blinco . “Living characteristics of the free-radical ring-closing polymerization of diallyldimethylammonium chloride.” European Polymer Journal 47 1 (2011): Pages 111-114.
[2] Sivaprakash Shanmugam. “Catalyst-Free Selective Photoactivation of RAFT Polymerization: A Facile Route for Preparation of Comblike and Bottlebrush Polymers.” Macromolecules 51 19 (2018): 7776–7784.
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| | DoPAT Preparation Products And Raw materials |
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