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| | 1H,1H,2H,2H-Heptadecafluorodecyl acrylate Basic information |
| Product Name: | 1H,1H,2H,2H-Heptadecafluorodecyl acrylate | | Synonyms: | 1,1,2,2-Tetrahydroperfluorodecylacrylate;2-propenoicacid,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylest;2-Propenoicacid,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylester;ACRYLIC ACID 1H,1H,2H,2H-HEPTADECAFLUORO-N-DECYL ESTER;ACRYLIC ACID 1H,1H,2H,2H-PERFLUORODECYL ESTER;1H,1H,2H,2H-HEPTADECAFLUORO-N-DECYL ACRYLATE;1H,1H,2H,2H-HEPTADECAFLUORODECYL ACRYLATE;DAIKIN R-1820 | | CAS: | 27905-45-9 | | MF: | C13H7F17O2 | | MW: | 518.17 | | EINECS: | 248-722-7 | | Product Categories: | monomer;Fluorous Chemistry;Fluorous Compounds;Synthetic Organic Chemistry | | Mol File: | 27905-45-9.mol |  |
| | 1H,1H,2H,2H-Heptadecafluorodecyl acrylate Chemical Properties |
| Melting point | -3°C | | Boiling point | 90 °C4 mm Hg(lit.) | | density | 1.637 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.337(lit.) | | Fp | >230 °F | | storage temp. | 2-8°C | | solubility | Chloroform, Methanol (Slightly), Water (Sparingly) | | form | Liquid | | color | Clear colorless | | Specific Gravity | 1.596 | | BRN | 5173337 | | Stability: | Light Sensitive | | InChIKey | QUKRIOLKOHUUBM-UHFFFAOYSA-N | | CAS DataBase Reference | 27905-45-9(CAS DataBase Reference) | | EPA Substance Registry System | 1,1,2,2-Tetrahydroperfluorodecyl acrylate (27905-45-9) |
| | 1H,1H,2H,2H-Heptadecafluorodecyl acrylate Usage And Synthesis |
| Chemical Properties | clear colorless liquid | | Uses | (Perfluorooctyl)ethyl Acrylate is a reagent used in the synthesis of parahydrophobic polymer coatings, as well as polymer brushes for controlling surface lubrication. | | Definition | 1H,1H,2H,2H-Heptadecafluorodecyl acrylate is a semi-volatile fluorinated organic compound and is in polluted air in Asia and the western United States during the spring. The structure of this substance contains multiple fluorine atoms and a terminal olefin unit. It has high chemical reactivity and is sensitive to intense light. Perfluorooctylethyl acrylate contains an unsaturated double-bond unit and can be used to prepare perfluoroacrylate polymers. | | Application | 1H,1H,2H,2H-Heptadecafluorodecyl acrylate can be applied as follows:
(1) Coatings Industry: Due to their low surface tension and excellent heat resistance, 1H,1H,2H,2H-Heptadecafluorodecyl acrylate are commonly used in the preparation of high-performance surface coatings, such as water-repellent, oil-repellent, corrosion-repellent, anti-adhesive and temperature-resistant coatings[1-2].
(2) Lubricants: It can be used as a lubricant, especially where oil and water resistance is required.
(3) Surface Modifiers: In surface modification of textiles, plastics and other materials, it can provide special surface properties such as anti-staining and anti-adhesion[3].
(4) Electronic encapsulation material: Due to its chemical inertness and heat resistance, it can also be used as encapsulation material for electronic products, such as liquid crystal displays and fibre optic manufacturing. | | Research |
Latex based upon fluorinated acrylates such as perfluorooctylethyl methacrylate (FMA) and perfluorooctylethyl acrylate (FA; 1H,1H,2H,2H-Heptadecafluorodecyl acrylate) and fluorine-free acrylates such as n-butyl methacrylate (BMA) was prepared using emulsion polymerization in the presence of octadecyltrimethylammonium bromide (C18TAB) and 2,2′-azobis(2-amidinopropane) dihydrochloride (V50) as water-soluble azo initiator[4].
| | References |
[1] VIRENDRA KUMAR. Fluorocarbon Coatings Via Plasma Enhanced Chemical Vapor Deposition of 1H,1H,2H,2H‐perfluorodecyl Acrylate ‐ 2, Morphology, Wettability and Antifouling Characterization[J]. Plasma Processes and Polymers, 2010. DOI:10.1002/PPAP.201000038.
[2] N. YOSHINO. Syntheses and Reactions of Metal Organics. XVII. Synthesis of Silane Coupling Agent Having Fluorocarbon Chain and Surface Modification of Glass Plate[J]. Bulletin of the Chemical Society of Japan, 1993. DOI:10.1246/BCSJ.66.472.
[3] JIYOUNG LEE . Robust and superomniphobic core-shell SiO2@poly(1H,1H,2H,2H-heptadecafluorodecyl methacrylate-co-methyl methacrylate) coating materials synthesized by thiol lactam initiated radical polymerization[J]. Progress in Organic Coatings, 2020. DOI:10.1016/j.porgcoat.2020.105851.
[4] Reinhard F. Linemann. “Latex Blends of Fluorinated and Fluorine-Free Acrylates: Emulsion Polymerization and Tapping Mode Atomic Force Microscopy of Film Formation.” Macromolecules 32 6 (1999): 1715–1721.
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| | 1H,1H,2H,2H-Heptadecafluorodecyl acrylate Preparation Products And Raw materials |
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