- beta-Bromostyrene
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- $0.00 / 1kg
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2024-01-04
- CAS:103-64-0
- Min. Order: 1kg
- Purity: 0.99
- Supply Ability: 50000kg
- beta-Bromostyrene
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- $101.00 / 1KG
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2023-12-29
- CAS:103-64-0
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: g-kg-tons, free sample is available
- beta-Bromostyrene
-
- $1.00 / 1KG
-
2019-07-06
- CAS:103-64-0
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 200kg
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| | beta-Bromostyrene Basic information |
| | beta-Bromostyrene Chemical Properties |
| Melting point | 7 °C(lit.) | | Boiling point | 219-221 °C(lit.) | | density | 1.427 g/mL at 25 °C(lit.) | | vapor pressure | 16.4Pa at 25℃ | | refractive index | n20/D 1.608 | | Fp | 215 °F | | storage temp. | 2-8°C | | solubility | Soluble in alcohol. | | form | Liquid | | color | very deep green-yellow | | Odor | at 1.00 % in dipropylene glycol. strong leafy green hyacinth | | Odor Type | green | | Water Solubility | 56.624mg/L at 25℃ | | BRN | 2038495 | | LogP | 3.391 at 25℃ | | CAS DataBase Reference | 103-64-0(CAS DataBase Reference) | | NIST Chemistry Reference | Benzene, (2-bromoethenyl)-(103-64-0) | | EPA Substance Registry System | .beta.-Bromostyrene (103-64-0) |
| Hazard Codes | Xn | | Risk Statements | 22 | | Safety Statements | 23-24/25-36/37 | | WGK Germany | 3 | | RTECS | WL3850000 | | TSCA | Yes | | HS Code | 29039990 | | Hazardous Substances Data | 103-64-0(Hazardous Substances Data) | | toxicity | An acute oral LD50 in rats was reported as 1.25 ml/kg(0.82-189 ml/kg). The acute dermal LD50 was reported as > 6 ml/kg in the rabbit |
| | beta-Bromostyrene Usage And Synthesis |
| Chemical Properties | CLEAR YELLOWISH TO BROWN LIQUID | | Occurrence | Apparently has not been reported to occur in nature. | | Uses | Perfumery. | | Uses | Beta-Bromostyrene, cis + trans is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. | | Uses | β-Bromostyrene was used in the one-pot method for the preparation of cinnamonitriles. It was also used in the preparation of pure ethyl Z- and E-α,α-difluoro-4-phenyl-3-butenoate and 1,3-diphenyl-1-butene. It may be used in the synthesis of β-tert-butylstyrene via cross coupling reaction with tert-butylmagnesium chloride in the presence of dichloro[1,1′-bis(diphenylphosphino)ferrocene]nickel(II) catalyst. It may also be used to prepare γ-but-2-enolactone by reacting with nickel carbonyl in the presence of alkynes. | | Preparation | By the action of aqueous alkali on cinnamic acid dibromide. | | General Description | β-Bromostyrene is an α,β-unsaturated aromatic halide. It can be synthesized by catalytic Hunsdiecker reaction (CHR) of cinnamic acid. It is commonly utilized as a precursor for preparing substituted alkenes, corresponding acetylenes and also in the total synthesis of natural compounds and antibiotics. | | Flammability and Explosibility | Not classified |
| | beta-Bromostyrene Preparation Products And Raw materials |
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