(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE

(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE Suppliers list
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Products Intro: Product Name:(R)-(-)-2,2-Dimethyl-4-(hydroxymethyl)-1,3-dioxolane-p-toluenesulfonate
CAS:23788-74-1
Purity:98%(Min,HPLC) Package:1G;1KG;100KG
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Products Intro: Product Name:1,3-Dioxolane-4-methanol,2,2-dimethyl-, 4-(4-methylbenzenesulfonate), (4R)-
CAS:23788-74-1
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Products Intro: Product Name:[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl 4-methylbenzene-1-sulfonate
CAS:23788-74-1
Purity:0.97 Package:1KG;25KG
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Products Intro: CAS:23788-74-1
Purity:98% Package:5g; 25g; 100g; 500g; 1kg; 25kg
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Products Intro: Product Name:(R)-(-)-2,2-Dimethyl-4-(hydroxymethyl)-1,3-dioxolane-p-tolue...
CAS:23788-74-1
(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE Basic information
Product Name:(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE
Synonyms:p-Toluenesulfonic acid [(R)-2,2-dimethyl-1,3-dioxolane-4β-yl]methyl ester;p-Toluenesulfonic acid [R,(-)]-2,2-dimethyl-1,3-dioxolan-4-ylmethyl ester;p-Toluenesulfonic acid [R,(-)]-2,2-dimethyl-1,3-dioxolane-4-ylmethyl ester;(R)-(-)-2,2-Dimethyl-4-(hydroxymethyl)-1,3-dioxolane-p-toluenesulfonate,97%;p-Toluenesulfonic acid ((4R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl ester;Toluene-4-sulfonic acid ((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)methyl ester;D-α,β-Isopropylideneglycerol-γ-tosylate;D-(-)-1,2-ISOPROPYLIDENEGLYCEROL 3-(P-TOLUENESULFONATE)
CAS:23788-74-1
MF:C13H18O5S
MW:286.34
EINECS:
Product Categories:chiral;Chiral Building Blocks;Dioxanes & Dioxolanes;Dioxolanes;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry
Mol File:23788-74-1.mol
(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE Structure
(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE Chemical Properties
Melting point 41-43 °C(lit.)
Boiling point 398.71°C (rough estimate)
density 1.208 g/mL at 25 °C(lit.)
refractive index n20/D 1.506(lit.)
Fp >230 °F
storage temp. -20°C
solubility Dichloromethane; Chloroform; Ethyl Acetate; Methanol; DMF;
form Oil
color Pale Brown
optical activity[α]/D 7.0±0.5°, neat
BRN 89800
InChIKeySRKDUHUULIWXFT-LLVKDONJSA-N
CAS DataBase Reference23788-74-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-22
Safety Statements 26-36-37/39
WGK Germany 3
10-21
HS Code 29329900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE Usage And Synthesis
Chemical Propertiesclear yellow to light brown viscous liquid
Uses(R)-(-)-2,2-Dimethyl-1,3-dioxolan-4-ylmethyl p-Toluenesulfonate is a chiral building block. It is used to prepare the antifungal agent ketoconazole. It is also used to prepare acyclic Nucleotide Analogs Derived from 8-Azapurines with antiviral activities.
(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE Preparation Products And Raw materials
Preparation ProductsCis -Tosylate-->(S)-(+)-(2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL)-METHYLAMINE
Tag:(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE(23788-74-1) Related Product Information
(R)-2-(2-(methylthio)ethyl)azetidine-2-carboxylic acid (R)-2-Octyl 4-[4-(Hexyloxy)benzoyloxy]benzoate (R)-2-(2-(methylthio)ethyl)pyrrolidine-2-carboxylic acid (R)-2-(2-methoxyphenyl)-2-((tetrahydro-2H-pyran-4-yl)oxy)ethan-1-ol (R)-2-((2-(hydroxydiphenylmethyl)pyrrolidin-1-yl)methyl)-6-(trifluoromethyl)phenol ((R)-morpholin-2-yl)methanol (R)-2-(hydroxymethyl)-1-methylpiperazine (-)-1,4-DI-O-TOSYL-2,3-O-ISOPROPYLIDENETHREITOL (S)-(+)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE (R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE cis-[2-(2,4-Dichlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)-1,3-dioxolan-4-yl]methyl-p-toluenesulfonate 2,2-DIMETHYL-1,3-DIOXOLANE Methyl p-toluenesulfonate 1,3-Dioxolane-4-methanol (R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol 2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE 2,3-O-Isopropylidene-1,6-ditosyl-L-sorbose (-)-TRANS-1-O-TOSYL-2,3-ISOPROPYLIDENE-L-THREITOL