|
|
| | 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Basic information | | Reactions |
| Product Name: | 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos | | Synonyms: | 2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl;2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%;2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos);BrettPhos 96%;2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos;2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl;Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine;Dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine | | CAS: | 1070663-78-3 | | MF: | C35H53O2P | | MW: | 536.77 | | EINECS: | | | Product Categories: | Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts | | Mol File: | 1070663-78-3.mol |  |
| | 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Chemical Properties |
| Melting point | 191-193℃ | | Boiling point | 607.7±55.0 °C(Predicted) | | storage temp. | Refrigerator, under inert atmosphere | | solubility | Chloroform (Slightly), Methanol (Slightly, Sonicated) | | form | crystal | | color | white | | InChIKey | WDVGNXKCFBOKDF-UHFFFAOYSA-N | | SMILES | P(C1CCCCC1)(C1CCCCC1)C1=C(OC)C=CC(OC)=C1C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C |
| Risk Statements | 36/37/38 | | Safety Statements | 26-37-60 | | WGK Germany | nwg | | TSCA | No | | HS Code | 2931499090 |
| | 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Usage And Synthesis |
| Reactions |
- Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
- Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
- Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
- Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
- Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
- Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
- Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
- Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.
| | Uses | Ligand for the Suziki-Miyaura coupling of tosylates and mesylates. | | Uses | Buchwald Phosphine Ligands for chemical Synthesis |
| | 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Preparation Products And Raw materials |
|