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Triiron tetraoxide

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CAS:1317-61-9
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Triiron tetraoxide manufacturers

  • Triiron tetraoxide
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  • $30.00 / 1kg
  • 2023-10-16
  • CAS:1317-61-9
  • Min. Order: 1kg
  • Purity: 0.99
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  • Triiron tetraoxide
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  • 2023-09-06
  • CAS:1317-61-9
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  • Purity: 99%
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  • Triiron tetraoxide
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  • $0.00 / 1kg
  • 2023-08-30
  • CAS:1317-61-9
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  • Purity: 0.99
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Triiron tetraoxide Basic information
Physical Properties Occurrence and Uses Preparation Reactions
Product Name:Triiron tetraoxide
Synonyms:Iron(II,III) oxide, 98% (metals basis);Iron(II,III) oxide, 97% (metals basis);Iron(II,III) oxide, 99.95% (metals basis);Iron(II,III) oxide: (Ferrosoferric oxide: Iron(III) oxide);Iron (II, III) oxide, 99.5% min (metals basis);Iron (II,III) oxide, 96% (metals basis) Synthetic black iron oxide;Iron(II,III) oxide, Puratronic, 99.997% (metals basis);Iron oxide, magnetic nanoparticles solution
CAS:1317-61-9
MF:Fe3O4-2
MW:231.53
EINECS:215-277-5
Product Categories:nano structured material;metal oxide;Inorganics
Mol File:1317-61-9.mol
Triiron tetraoxide Structure
Triiron tetraoxide Chemical Properties
Melting point 1538 °C(lit.)
density 4.8-5.1 g/mL at 25 °C(lit.)
refractive index 3.0
Fp 7 °C
storage temp. -20°C
solubility Aqueous Acid (Slightly)
form powder
color black
Specific Gravity5.2
Odorat 100.00?%. odorless
Water Solubility Insoluble in water and organic solvents. Soluble in concentrated mineral acids.
Merck 14,4040
Stability:Stable. Incompatible with strong acids, chloroformates, peroxides.
CAS DataBase Reference1317-61-9(CAS DataBase Reference)
NIST Chemistry ReferenceIron(ii,iii) oxide(1317-61-9)
EPA Substance Registry SystemIron oxide (Fe3O4) (1317-61-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
RIDADR 3
WGK Germany -
TSCA Yes
HS Code 28211000
MSDS Information
ProviderLanguage
Magnetic iron oxide English
SigmaAldrich English
ALFA English
Triiron tetraoxide Usage And Synthesis
Physical PropertiesBlack cubic crystal or amorphous powder; refractive index 2.42; density 5.17 g/cm3; Moh’s hardness 6.0; melts at 1,597°C; insoluble in water, soluble in acids.
Occurrence and UsesTriiron tetroxide occurs in nature as the mineral magnetite, the magnetic oxide of iron. This mineral along with hematite is used as the starting material for producing iron, steel and other ferro-alloys.
PreparationTriiron tetroxide is obtained from its natural mineral magnetite. In the laboratory the compound may be prepared by adding sodium hydroxide solution to an aqueous solution of 1:2 molar mixture of ferrous and ferric salt. (i.e., 1 mol FeCl2 + 2 mol FeCl3). The resulting black precipitate of the hydroxide on heating dehydrates to gives triiron tetroxide:
Fe2+(aq) + 2Fe3+(aq) + 8OH¯(aq) → Fe3(OH)8(s)
Fe3(OH)8(s) → Fe3O4(s) + 4H2O(g)
Also, the tetroxide may be produced by partial oxidation of iron or iron(II) sulfate by heating under limited amount of air. Another method of production involves heating iron metal with steam:
3Fe + 4H2O → Fe3O4 + 4H2
ReactionsTriiron tetroxide, when heated at elevated temperatures with a reducing agent such as hydrogen or carbon monoxide in the absence of air, produces metallic iron:
Fe3O4 + 4H2 → 3Fe + 4H2O
Partial reduction gives iron(II) oxide. When treated with concentrated acids, the tetroxide dissolves in acids forming mixtures of iron(II) and iron(III) salts:
Fe3O4 + 8HCl → FeCl2 + 2FeCl3 + 4H2O
Fe3O4 + 4H2SO4 → FeSO4 + Fe2(SO4)3 + 4H2O
Chemical PropertiesMagnetite (Fe3O4) constitutes the richest ore of iron; it is black and magnetic, one variety being called "lodestone".
Chemical Propertiessolid
UsesIron(II,III) oxide (Fe3O4) can be used as a heterogeneous catalyst for the Fenton type oxidation of rhodamine B. It can be used as an anode material for the fabrication of lithium-ion batteries. Fe3O4 can also be utilized in the catalysis of the oxygen reduction reaction (ORR) in the anion exchange membrane fuel cell.
UsesMostly it is used as a black- pigment -catalyst in the Haber process and in the water gas shift reaction. It is used as a contrast-agent in MRI scanning, whereas it is used as a pigment in magnetic applications, polishing compounds, cosmetics, medicines, polymer, rubber, filler, building, construction, appliances, and magnetic inks.
UsesTriiron tetraoxide can be used as pigment in paints, linoleum, ceramic glazes; in coloring glass; as a polishing compound; in the textile industry; in cathodes; as catalyst.
General DescriptionConcentration 5mg/ml includes total weight nanocrystals plus ligands.
Flammability and ExplosibilityNon flammable
Properties and Applications

TEST ITEMS

SPECIFICATION

APPEARANCE

BLACK POWDER

CONTENT OF Fe 3 O 4

90% min

pH VALUE

5-8

DENSITY

4.5 g/ml

SHADE

CLOSE TO STANDARD

OIL ABSORPTION

10-20%

RESIDUE ON 320 MESH

0.3% max

WATER SOLUBLE

0.3% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

98-102 %

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