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Quinhydrone

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CAS:106-34-3
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Quinhydrone manufacturers

  • Quinhydrone
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  • CAS:106-34-3
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  • Quinhydrone
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  • 2021-06-23
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  • Quinhydrone
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  • 2020-09-03
  • CAS:106-34-3
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Quinhydrone Basic information
Product Name:Quinhydrone
Synonyms:2,5-Cyclohexadiene-1,4-dione, compd. with 1,4-benzenediol (1:1);2,5-Cyclohexadiene-1,4-dione,compd.with1,4-benzenediol(1:1);2,5-CYCLOHEXADIENE-1,4-DIONE CMPD WITH 1,4-BENZENEDIOL;Quinhydrone;2,5-Cyclohexadiene-1,4-dionecompdwith1,4-benzenediol(1:1);Greenhydroquinone;BALSAM CANADA, FILTERED FOR MICROSCOPY;QUINHYDRONE 98+% FOR ANALYTICAL PURPOSE;QuinhydroneGr;p-benzoquinone hydroquinone complex
CAS:106-34-3
MF:C12H10O4
MW:218.21
EINECS:203-387-6
Product Categories:Hydroquinone;API intermediates;Benzoquinones
Mol File:106-34-3.mol
Quinhydrone Structure
Quinhydrone Chemical Properties
Melting point 167-172 °C (lit.)
Boiling point 285 °C
density 1.32
refractive index 1.4270 (estimate)
storage temp. Store below +30°C.
solubility 4g/l
form Crystalline Powder
Specific Gravity0.863 (20/4℃)
color Dark green
Water Solubility 4 g/L (20 ºC)
Sensitive Light Sensitive
Merck 14,8058
BRN 3919222
Stability:Stable. Incompatible with strong oxidizing agents.
LogP0.644 (est)
CAS DataBase Reference106-34-3(CAS DataBase Reference)
NIST Chemistry ReferenceQuinhydrone(106-34-3)
EPA Substance Registry SystemQuinhydrone (106-34-3)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-36/37/38-50
Safety Statements 26-36-61-37/39-29
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
RTECS VA4550000
TSCA Yes
HS Code 2942 00 00
HazardClass 6.1
PackingGroup III
ToxicityLD50 orally in rats: 225 mg/kg (Woodward)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Quinhydrone Usage And Synthesis
Chemical Propertiesa dark green crystalline powder which is a complex formed by benzoquinone and hydroquinone.
Quinhydrone
Quinhydrone is a general reagent used in potentiometric titrations. It can also be used as a π-acceptor in the formation of charge-transfer complex of analytes for spectrophotometric analysis.
UsesIn pH determinations (quinhydrone electrode).
UsesUsed to measure the hydrogen ion concentration (pH) of a solution in a chemical experiment. It provides an alternative to the commonly used glass electrode in a pH meter.
UsesQuinhydrone is a hydrogen bonded 1:1 charge transfer complex of hydroquinone and p-benzo-quinone having semiconducting properties.
Quinhydrone is addition compound of one mol hydroquinone and one mol Benzoquinone.
Quinhydrone electrode is a type of redox electrode which can be used to measure the hydrogen ion concentration (pH) of a solution in a chemical experiment.
Quinhydrone/methanol treatment for the measurement of carrier lifetime in crystalline silicon substrates has been reported. Surface passivation of silicon substrates by quinhydrone/ethanol treatment has been investigated.
DefinitionChEBI: Quinhydrone is an addition compound. It contains a 1,4-benzoquinone and a hydroquinone.
DefinitionThe so-called quinhydrone electrode, containing equivalent amounts of p-benzoquinone and hydroquinone, is used to determine hydrogen ion concentrations of unknown solutions. Hydroquinone is used principally as a photographic developing agent. The main advantages of the quinhydrone electrode are low internal resistance, rapid response, high accuracy, simplicity, free of errors due to the presence of nonreducing gases, and free of salt errors. Major limitations are that it contaminates the solution, cannot be used to monitor a flowing solution, the solution must be free of strong oxidizing and reducing agents, and it is limited to a pH range of 1 to 9. In alkaline solution, the weakly acidic H2Q is neutralized and is subject to oxidation by air and dissolved oxygen. The main application of the quinhydrone electrode is in nonaqueous solvents where reproducible results are obtained in a variety of solvents. The tetra-chloro derivative (chloranil electrode) is even more useful.
General DescriptionQuinhydrone/methanol treatment for the measurement of carrier lifetime in crystalline silicon substrates has been reported. Surface passivation of silicon substrates by quinhydrone/ethanol treatment has been investigated.
HazardToxic by ingestion.
Purification MethodsCrystallise quinhydrone from H2O at 65o , then dry it in vacuo.[Beilstein 7 H 617, 7 IV 2069.]
Quinhydrone Preparation Products And Raw materials
Raw materialsFERROUS SULFATE-->Ammonium iron(III) sulfate
Tag:Quinhydrone(106-34-3) Related Product Information
1,4-Benzoquinone tert-Butylhydroquinone Trimethylhydroquinone Idebenone VITAMIN K4 Chloranil 2-Methylhydroquinone Hydroquinone 1,6-Dibromohexane Butoxybenzene Quinacridone MERCURY(II) SULFATE Quinoline saframycin Mx1 Quinhydrone Hydroquinonesulphonicacidsodiumsalt