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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

CAS No.
742103-27-1
Chemical Name:
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
Synonyms
Mo-Phos;cBRIDP[R];cBRIDP(regR);cBRIDP®cBRIDP(regR) >ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane;Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine;Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine;Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP;Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)-
CBNumber:
CB11181097
Molecular Formula:
C24H33P
Molecular Weight:
352.49
MDL Number:
MFCD09753012
MOL File:
742103-27-1.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Properties

Melting point 87-91°C
Boiling point 427.3±45.0 °C(Predicted)
form solid
color white to pale yellow
Sensitive air sensitive, store cold
CAS DataBase Reference 742103-27-1

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335-H302+H312+H332-H315
Precautionary statements  P280-P301+P312-P362+P364
WGK Germany  3
HS Code  2931499090

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical C2979 cBRIDP(regR) >97.0%(HPLC) 742103-27-1 1g $117 2021-12-16 Buy
TCI Chemical C2979 cBRIDP(regR) >97.0%(HPLC) 742103-27-1 200mg $34 2021-12-16 Buy
Strem Chemicals 15-1005 Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP 742103-27-1 250mg $33 2021-12-16 Buy
Strem Chemicals 15-1005 Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP 742103-27-1 1g $98 2021-12-16 Buy
Strem Chemicals 15-1005 Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP 742103-27-1 5g $303 2021-12-16 Buy
Product number Packaging Price Buy
C2979 1g $117 Buy
C2979 200mg $34 Buy
15-1005 250mg $33 Buy
15-1005 1g $98 Buy
15-1005 5g $303 Buy

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Chemical Properties,Uses,Production

Reactions

  1. Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
  2. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
  3. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction. 
Reactions of 742103-27-1

Uses

Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.

General Description

This product has been enhanced for catalytic efficiency.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 34)Suppliers
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Zhengzhou Alfa Chemical Co.,Ltd
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Career Henan Chemica Co
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LEAPCHEM CO., LTD.
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Amadis Chemical Company Limited
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J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24539 81
BeiJing Hwrk Chemicals Limted 0757-86329057 18501085097 sales3.gd@hwrkchemical.com China 7583 55
TCI AMERICA 800-4238616 sales@tciamerica.com Americas 23662 75
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP cBRIDP(regR) Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP® Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)- cBRIDP[R] Bis-(1,1-dimethylethyl)-(1-methyl-2,2-diphenylcyclopropyl)-phosphine Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane cBRIDP(regR) > Mo-Phos 742103-27-1 Achiral Phosphine Aryl Phosphine organophosphine ligand