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| | TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Basic information |
| Product Name: | TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE | | Synonyms: | tris(3,5-dimethylphenyl)-phosphin;TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE;TRIS(3,5-XYLYL)PHOSPHINE;TRI(3,5-XYLYL)PHOSPHINE;Tris(3,5-dimethylphenyl)phosphine,98%;TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE, 97+%;Tri(3,5-dimethylphenyl)phosphine;Tris(3,5-dimethylphenyl)phosphineTris(3,5-xylyl)phosphine | | CAS: | 69227-47-0 | | MF: | C24H27P | | MW: | 346.44 | | EINECS: | 624-162-2 | | Product Categories: | Aryl Phosphine;Achiral Phosphine;organophosphorus ligand;Ligand;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds | | Mol File: | 69227-47-0.mol |  |
| | TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Chemical Properties |
| Hazard Codes | Xn | | Risk Statements | 22 | | Safety Statements | 26-36/37/39-22 | | WGK Germany | 3 | | TSCA | Yes | | HS Code | 29310099 |
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ACROS
| English |
| | TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powde | | Uses | Catalyst for:
- Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
- Highly selective rhodium-catalyzed hydrogenation reactions
- Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes
Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes
Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis |
| | TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Preparation Products And Raw materials |
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